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How Sodium Lignosulfonate Is Made from Sulfite Pulp Liquor

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sodium-lignosulfonate-light

Sodium lignosulfonate is produced from the spent liquor of sulfite pulping. The liquor contains dissolved lignosulfonate, wood sugars and inorganic salts; refining turns it into a consistent powder or liquid grade.

From Spent Liquor to Powder

  1. Collect spent sulfite liquor after the pulp has been separated.
  2. Convert to the sodium salt if the mill cooks with calcium: the calcium is exchanged for sodium and removed as an insoluble calcium salt. This gives the low Ca + Mg that sodium grades are specified for.
  3. Reduce sugars where needed, for example by fermentation, because sugars retard cement setting.
  4. Concentrate by evaporation to a liquid grade.
  5. Spray-dry to a free-flowing powder.

How Production Shows Up in the Specification

ParameterSodium LS Grade One (GAC-NaLS-1)Why it matters
Lignosulfonate content55% min (dry basis)Active material
Calcium & magnesium0.5% maxShows the sodium conversion; matters in sulfate- or phosphate-rich systems
Reducing sugar7% maxAffects concrete setting time
Water-insoluble matter1.5% maxFibres and impurities
Sulphate2–5%Inorganic salt from processing
Moisture5% maxDrying quality
Typical values from the GAC-NaLS-1 TDS; the COA of each lot prevails.

Liquid sodium lignosulfonate (for example our dust-control grade, 45% min solids) skips the drying step. Product details: sodium lignosulfonate. Background: from lignin to lignosulfonate.

Powder or Liquid?

PowderLiquid
SolidsAbout 95% dry matterAbout 45–50% solids
HandlingBags; dissolve before usePump directly; protect from freezing
Transport cost per unit of activeLowerHigher (water is shipped)
Typical buyersExport, dry-mix plantsLocal plants with tank storage

Both forms come from the same refined liquor; the choice depends on your dosing equipment and freight.

Frequently Asked Questions

How is sodium lignosulfonate made?

From spent sulfite pulping liquor: the lignosulfonate is converted to the sodium salt if needed, sugars are reduced, and the liquor is concentrated and spray-dried.

Why does sodium lignosulfonate have low calcium and magnesium?

Calcium is removed when the liquor is converted to the sodium salt. Our Grade One specifies Ca + Mg at 0.5% max.